全文获取类型
收费全文 | 99375篇 |
免费 | 16758篇 |
国内免费 | 11681篇 |
专业分类
化学 | 70044篇 |
晶体学 | 1073篇 |
力学 | 5724篇 |
综合类 | 667篇 |
数学 | 12589篇 |
物理学 | 37717篇 |
出版年
2024年 | 103篇 |
2023年 | 2002篇 |
2022年 | 2237篇 |
2021年 | 3196篇 |
2020年 | 4118篇 |
2019年 | 3877篇 |
2018年 | 3573篇 |
2017年 | 3214篇 |
2016年 | 4844篇 |
2015年 | 4682篇 |
2014年 | 5794篇 |
2013年 | 7538篇 |
2012年 | 9108篇 |
2011年 | 9481篇 |
2010年 | 6629篇 |
2009年 | 6357篇 |
2008年 | 6682篇 |
2007年 | 5970篇 |
2006年 | 5583篇 |
2005年 | 4660篇 |
2004年 | 3648篇 |
2003年 | 2876篇 |
2002年 | 2503篇 |
2001年 | 2140篇 |
2000年 | 1834篇 |
1999年 | 1977篇 |
1998年 | 1677篇 |
1997年 | 1519篇 |
1996年 | 1490篇 |
1995年 | 1348篇 |
1994年 | 1233篇 |
1993年 | 990篇 |
1992年 | 894篇 |
1991年 | 772篇 |
1990年 | 646篇 |
1989年 | 501篇 |
1988年 | 372篇 |
1987年 | 334篇 |
1986年 | 330篇 |
1985年 | 261篇 |
1984年 | 187篇 |
1983年 | 152篇 |
1982年 | 125篇 |
1981年 | 78篇 |
1980年 | 59篇 |
1979年 | 24篇 |
1978年 | 22篇 |
1976年 | 22篇 |
1975年 | 22篇 |
1957年 | 26篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
将具有完备动力学理论的非连续变形分析(DDA)方法应用于块体碰撞研究。基于三维DDA(3D DDA)方法,按时步输出块体碰撞过程速度变化和接触嵌入量,进而得到块体碰撞恢复系数、冲量、冲击力。以此为参考指标,采用斜抛、面-面对心等碰撞模型,验证3D DDA方法模拟块体碰撞的有效性,并将3D DDA方法应用于多米诺骨牌倾倒、滚石边坡成灾及防护等算例分析,探讨了多米诺骨牌倾倒机制、滚石启动及运动行为、滚石灾害防护方案。结果表明:多米诺骨牌间距越大,同一块体被碰撞时间越迟,其最终稳定时间也越迟,与下一块体碰撞的动能越大;滚石运动呈侧向平动及转动三维运动特征,每一次碰撞,均引起动能、轨迹或状态的显著变化;滚石拦挡设施弹簧刚度越大,越先达到最大冲击力,最大冲击力随弹簧刚度的增加而减小;可结合树木阻挡效应,耗散滚石动能,降低滚石飞跃高度,使滚石灾害减轻或控制在防护范围以内。 相似文献
102.
X-ray imaging functionalization of biodegradable polyesters is a great demand and challenge in biomedical applications.In this work,a strategy of in-chain functionalization through the combination of ring opening copolymerization and oxime "Click" postfunctionalization was developed towards X-ray opaque polylactide copolymers.A functionalized cyclic carbonate was first synthesized and used as comonomer of polylactide copolymers,which were subjected to postfunctionalization of oxime "Click" reaction towards iodinated polylactide copolymers.The chemical structure and physical properties of the target products were traced and confirmed.In vitro cytotoxicity evaluation with 3T3-Swiss albino by Alamar blue demonstrated a low cytotoxicity.The X-ray radiopacity was analyzed by Micro-CT and quantified by Hounsfield Units value,which could be tailorable by the feedstock.It is a promising X-ray visible implantable biomaterial in biomedical applications. 相似文献
103.
Zhang Yaohui Li Tianbin Feng Wenkai Xiong Zuqiang Zhang Guoqiang 《Journal of Thermal Analysis and Calorimetry》2020,139(1):47-56
Journal of Thermal Analysis and Calorimetry - In order to find out the rules of the effect of temperature on performances and hydration process of sulphoaluminate cement-based dual liquid grouting... 相似文献
104.
Li Jiaojiao Mohammadi Amin Maleki Akbar 《Journal of Thermal Analysis and Calorimetry》2020,139(4):2691-2703
Journal of Thermal Analysis and Calorimetry - Microgas turbines are one of the most well-known technologies for distributed generation. Unfortunately, their efficiency is not as high as it should... 相似文献
105.
106.
Sha Xia Dan Wang Nian-Ke Chen Dong Han Xian-Bin Li Hong-Bo Sun 《Annalen der Physik》2020,532(3):1900318
Defects play a central role in controlling the electronic properties of two-dimensional (2D) materials and realizing the industrialization of 2D electronics. However, the evaluation of charged defects in 2D materials within first-principles calculation is very challenging and has triggered a recent development of the WLZ (Wang, Li, Zhang) extrapolation method. This method lays the foundation of the theoretical evaluation of energies of charged defects in 2D materials within the first-principles framework. Herein, the vital role of defects for advancing 2D electronics is discussed, followed by an introduction of the fundamentals of the WLZ extrapolation method. The ionization energies (IEs) obtained by this method for defects in various 2D semiconductors are then reviewed and summarized. Finally, the unique defect physics in 2D dimensions including the dielectric environment effects, defect ionization process, and carrier transport mechanism captured with the WLZ extrapolation method are presented. As an efficient and reasonable evaluation of charged defects in 2D materials for nanoelectronics and other emerging applications, this work can be of benefit to the community. 相似文献
107.
Xin Xiangjun Wang Zhuo Yang Qinglan Li Fagen 《International Journal of Theoretical Physics》2020,59(3):918-929
International Journal of Theoretical Physics - Designated verifier signatures are very useful in the applications such as e-voting and auction. In this paper, an identity-based quantum designated... 相似文献
108.
109.
Nonlinear Dynamics - This paper considers the distributed adaptive neural consensus tracking control problem for a class of uncertain nonaffine nonlinear multi-agent systems. By making use of the... 相似文献
110.
Mohit Jaiswal Trang T. Tran Qingjiang Li Xin Yan Mingwei Zhou Krishnendu Kundu Gail E. Fanucci Zhongwu Guo 《Chemical science》2020,11(46):12522
Metabolic glycan engineering (MGE) coupled with nitroxide spin-labeling (SL) was utilized to investigate the heterogeneous environment of cell surface glycans in select cancer and normal cells. This approach exploited the incorporation of azides into cell surface glycans followed by a click reaction with a new nitroxide spin label. Both sialic acid and N-acetylglucosamine (GlcNAc) were targeted for spin labelling. Although each of these moieties experiences a diverse and heterogeneous glycan environment, their EPR spectra and hence mobility are both characterized as a linear combination of two distinct spectra where one component reflects a highly mobile or uncrowded micro-environment with the second component reflecting more restricted motion, reflective of increased crowding and packing within the glycocalyx. What differs among the spectra of the targeted glycans is the relative percentage of each component, with sialic acid moieties experiencing on average an ∼80% less crowded environment, where conversely GlcNAc/GalNAz labeled sites reported on average a ∼50% more crowded environment. These distinct environments are consistent with the organization of sugar moieties within cellular glycans where some residues occur close to the cell membrane/protein backbone (i.e. more restricted) and others are more terminal in the glycan (i.e. more mobile). Strikingly, different cell lines displayed varied relative populations of these two components, suggesting distinctive glycan packing, organization, and composition of different cells. This work demonstrates the capability of SDSL EPR to be a broadly useful tool for studying glycans on cells, and interpretation of the results provides insights for distinguishing the differences and changes in the local organization and heterogeneity of the cellular glycocalyx.Metabolic glycan engineering (MGE) coupled with nitroxide spin-labeling (SL) was utilized to investigate the heterogeneous environment of cell surface glycans in select cancer and normal cells. 相似文献